Insights into the Formation, Chemical Stability, and Activity of Transient NiyP@NiO x Core-Shell Heterostructures for the Oxygen Evolution Reaction

Wilde, P. and Dieckhöfer, S. and Quast, T. and Xiang, W. and Bhatt, A. and Chen, Y.-T. and Seisel, S. and Barwe, S. and Andronescu, C. and Li, T. and Schuhmann, W. and Masa, J.

Volume: 3 Pages: 2304-2309
DOI: 10.1021/acsaem.9b02481
Published: 2020

NiyP emerged as a highly active precatalyst for the alkaline oxygen evolution reaction where structural changes play a crucial role for its catalytic performance. We probed the chemical stability of NiyP in 1 M KOH at 80 °C and examined how exposure up to 168 h affects its structure and catalytic performance. We observed selective P-leaching and formation of NiyP/NiOx core-shell heterostructures, where shell thickness increases with ageing time, which is detrimental for the activity. By tuning the particle size, we demonstrate that prevention of complete catalyst oxidation is essential to preserve the outstanding electrochemical performance of NiyP in alkaline media. © 2020 American Chemical Society.

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